在鈀催化下通過導(dǎo)向基團（如吡啶和嘧啶）進行C-H位乙酰氧基化的反應(yīng).1,6
催化循環(huán)
反應(yīng)實例
苯醌在反應(yīng)中起到關(guān)鍵的促進作用。
在鈀催化的C-H鍵官能團化得過程中導(dǎo)向基團的作用非常顯著。
參考文獻
1. Dick, A. R.; Hull, K. L.; Sanford, M. S. J. Am. Chem. Soc. 2004, 126, 2300–2301.Melanie S. Sanford was born in New Bedford, MA, in 1975. She received a B.S. and M.S. in chemistry from Yale University in 1996 before obtaining her Ph.D. at California Institute of Technology with Professor Robert Grubbs in 2001. She then completed postdoctoral studies at Princeton University working with Professor John Groves. In 2003, she joined the faculty of the University of Michigan where she is currently the Moses Gomberg Collegiate Professor of Chemistry as well as Arthur F. Thurnau Professor of Chemistry. Her research program focuses on the development of new catalysts and catalytic transformations for applications in the synthesis of useful organic molecules.（Sanford1975年生于馬薩諸塞州的 New Bedford。1996年獲得了耶魯大學(xué)的化學(xué)學(xué)士和化學(xué)碩士學(xué)位，2001年在加州理工 Robert Grubbs教授下面獲得Ph.D. 。她后來又在普林斯頓大學(xué) John Groves教授處工作，并完成了博士后研究。2003年在密歇根大學(xué)任教，并很容易的獲得了Moses Gomberg Collegiate Professor of Chemistry 和 Arthur F. Thurnau Professor of Chemistry。她研究的重點是新型催化劑，并用以合成有用的有機分子。）
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編譯自：J.J. Li, Name Reactions: A Collection of Detailed Mechanisms and Synthetic Applications, Sanford reaction，page 115-116.
